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The neat episulfide of benzyl thiirane ether (BTE) resin was synthesized by the reaction of benzyl glycidyl ether (BGE) epoxy resin and KSCN under the microwave atmosphere at low temperature. The ring opening kinetic behaviors of neat BGE and neat BTE with polyether amine (D230) as the hardener were comparatively investigated by non-isothermal differential scanning calorimetry(DSC), and analyzed by...
A series of regular and tunable rigid–flexible crosslinking networks have been prepared to investigate shape memory effects. The tunable rigid–flexible epoxy resins (TRFEPs) were synthesized by ultraviolet light thiol–ene click chemistry. The FTIR and 1H NMR measurements indicated that TRFEPs were successfully synthesized. The thermal, thermomechanical, mechanical, and shape memory properties of all...
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