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Nanocomposites derived from a cross-linked melamine-formaldehyde polymer matrix and silver nanoparticles (AgNP) were prepared in situ. An interaction between Ag+ ions and AgNP with fragments of the 1,3,5-triazine polymer matrix was established. The mean diameter of the AgNP consisting of nanocrystal aggregates in the nanocomposites did not exceed 60 nm and was independent of the type of silver precursor...