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The solubility properties of ZnCl2/ZnAc2/ZnSO4-Met-H2O systems at 25°C in the whole cocentration range have been investigated by phase equilibrium method. The results indicate that ZnAc2 and ZnSO4 systems are both simple systems, which do not exist any compound; there are 2 complexes formed in ZnCl2 system: Zn(Met)Cl2 and Zn(Met)2Cl2· 2H2O. Under the direction of phase equilibrium result, 2 solid...