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The kinetics of molecular oxygen electroreduction were studied on platinum surfaces modified by tin underpotential deposition. The surface process was analysed by cyclic voltammetry in aqueous 10−4 M tin(II)/1 M sulfuric acid in the 0.05 to 0.70 V vs RHE range. Platinum sites involving (1 1 0) planes are mainly related to tin underpotential deposition as observed in the hydrogen sorption region. Kinetic...
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