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The oxyfunctionalization of n-hexane by aqueous H 2 O 2 was found to proceed substantially faster over a titanium-containing pentasil type catalyst denoted as TS-PQ(TM) (a trademark of PQ corporation for this titanium silicate material), than over other comparable titanium-containing zeolites. This catalyst has an unprecedented >99% efficiency in utilizing H 2 O 2 ...
The title reaction was studied over three TS-1 type catalysts at atmospheric pressure and at temperatures from 40 to 60 o C. By monitoring the consumption of H 2 O 2 continuously we found that the selective oxidation of n-hexane to 2- and 3-hexanols and -hexanones proceeds usually faster than previous experiments suggest, but the reaction stops before reaching total hydrocarbon...
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