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Heterogeneous copper/alumina catalysts with MgO, CaO, SrO, and BaO were prepared by co-precipitation synthesis method and characterized by means of N2-sorption, X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and subsequent H2 temperature-programmed reduction (H2 TPR) and H2/CO2 temperature-programmed desorption (H2 and CO2 TPD). The incorporation of oxides increases the metallic...
Heterogeneous catalytic hydrogenation of gaseous carbon dioxide to methanol is an important reduction reaction in chemical process engineering, renewable energy industry and emerging green chemistry, as it provides means to harness surplus electrical energy and convert a pollutant and emitted greenhouse gas into a useful building block and biofuel. On industrial operating scale, multifunctional copper/zinc...
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