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We investigated the microstructures formed in aqueous solutions of the cationic amino acid-based monomeric, methyl ester of N α -lauroyl arginine (LAM) and its dimeric molecules (C n (LA) 2 ), and examined the effect of a perturbation of the local arrangement of polar heads, by the spacer length, on the micellar and mesomorphic properties of surfactants in aqueous solutions...