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A new oxo-centered heterotrinuclear complex [Cr 2 MnO(PhCOO) 6 Py 3 ][CrO 3 Cl] was synthesized, which exhibited weak antiferromagnetic interaction between three atoms Cr III , Cr III and Mn III . The J values for Cr III --Mn III and Cr III --Cr II ...
An oxo-bridged binuclear iron(III) complex, [Fe(phen) 2 PhCOO] 2 OCl 2 7H 2 O, was synthesized and the crystal structure indicated that two octahedrally coordinated iron(III) ions bridged with oxygen atoms formed a non-linear complex. The bond angle of Fe--O--Fe is 155.6°. The studies of magnetic properties showed that there was strong antiferromagnetic superexchange...
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