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The mechanism of the elimination of CH 2 O and C 2 H 4 O from the molecular ions of benzaldoxime-O-n-propyl ether (1) was studied using specifically deuterated derivatives, methods of tandem mass spectrometry, and ab initio calculation of the minimum energy reaction path (MERP) at the B3LYP/6-311G * //UHF/3-21G * level of theory. The results show that the eliminated...