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Carbonyl carbyne complexes [L R (CO) 2 M C-p-tol], M = Mo, W, containing the tripodal oxygen ligands L -R = [(C 5 H 5 )Co{P(O)R 2 } 3 ] - , R = OMe, OEt, O-i-Pr, are oxidised by dioxygen, sulfur, bromine and iodine with concomitant splitting of the metal carbon bond. The reaction with iodine leads to highly labile complexes,...