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Zirconium-based conversion treatment of zinc, aluminium and magnesium oxides have been studied in-situ using ATR-FTIR in a Kretschmann geometry. This set-up was coupled to an electrochemical cell, which allowed to obtain chemical and electrochemical information simultaneously as a function of conversion time. This elucidated the strong relation between physico-chemical surface properties and zirconium-based...
In the transition to environmentally friendly production, chromic acid anodizing is being replaced by sulfuric acid, phosphoric acid or phosphoric‐sulfuric acid anodizing. While it is known that using these acids leads to the incorporation of anions into the oxide, little is known on how they affect the nature of the oxide and how this, in turn, affects the interactions across the oxide‐primer interface...
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