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The working mechanism of a ceria-supported Cu (Cuat:Ceat = 1:10) system in the Catalytic Wet Oxidation (CWO) of phenol with O2 (TR, 130–170 °C; PO2, 7 atm) has been thoroughly assessed. Basic relationships amongst pH, extent of leaching and rate of phenol and TOC conversion prove the major contribution of a homogeneous catalytic path by Cu ions on the peculiar CWO pattern of supported copper catalyst...
The activity-stability pattern of a 19wt.% Ni/MgO catalyst in the pre-reforming (T, 450 o C; P, 10bar) of n-hexane with steam (S/C, 1.5-3.5) in absence and presence of H 2 (H/C, 2) has been investigated. Deactivation profiles of the kinetics of CH 4 and CO/CO 2 formation indicate that the activity, selectivity and stability are closely related. Hydrogenation of carbon...
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