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In this work, we introduce a surface science approach to supported metal catalyst preparation utilizing thin, single-crystalline oxide films as substrates. The use of thin oxide films allows for combined morphological and chemical characterization of the sample at various steps of a typical catalyst preparation procedure. A Fe 3 O 4 -supported Pd model catalyst was prepared by impregnation...
The adsorption of carbon monoxide on Pt(111) was studied using polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) and sum frequency generation (SFG) spectroscopy. Two CO on-top signals at 2110cm −1 and 2097cm −1 have been detected under continuous CO exposure in a pressure range from 10 −7 to 100mbar and at temperatures between 200K and 300K. The...
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