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Solubility of methane, ethane, carbon monoxide and hydrogen in the linear alkane and 1-alkene homologous series is modeled using the Statistical Associating Fluid Theory (SAFT) equation of state (EOS) with a perturbed chain dispersion term (subsequently referred to as PC-SAFT). The pure component PC-SAFT parameters were obtained from the literature or, in the case of the higher alkenes (up to tetradecene),...
The effect of phase structure on the sorption and de-sorption of methylene chloride in poly(trimethylene terephthalate) was studied using low and high-crystallinity pellets (22 and 54%, respectively) as the starting material. Pellets were subjected to sorption for 12 days followed by de-sorption up to 7 months. During this cycle samples were removed periodically, weighed on a microbalance to assess...
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