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In the present study, theoretical analysis and electrolysis testing in the laboratory scale demonstrated the potential of Al metal production by electrolysis in a NaF-AlF3-Al2O3 melt with a cryolite ratio (CR; molar ratio of NaF/AlF3) of 1.3. Subsequently, the electrochemical processes of Al deposition on a tungsten cathode in this melt at 860 °C were comprehensively evaluated by cyclic voltammetry,...
A novel cathode with rectangular protrusions has been tested and implemented by Chinese industrial electrolytic aluminum smelters. Measurements of the protrusion wear rate and average cell voltage were conducted. Some experience was acquired with the aim of achieving better current efficiency and longer cathode lifetime. Furthermore, to investigate the influence of the novel cathode after wear down,...
Porous Ti2O3 was prepared via the carbothermal reduction of titanium dioxide using acetylene black or activated carbon as the reducing agent. The process was carried out at 1300–1350°C in a flowing argon atmosphere or vacuum. The reduced sample had a carbon content of less than 0.007% and a Ti2O3 content of more than 98% when 6.98% acetylene black or 8.88% activated carbon was used as the reducing...
Trapezoidal protrusions were added onto flat cathodes with the objective of enhancing the flow resistance to the metal in aluminum electrolysis cells. This design was tested for 8 months and proved to be effective in reducing cell voltage. Subsequently, trials revealed that when all the protrusions were widened, the energy consumption was barely influenced. Moreover, in the case of flat cathodes alternating...
A finite element model was developed to determine the impact of cathode material and shape on current density in an aluminum electrolysis cell. For the cathode material, results show that increased electrical resistivity leads to a higher cathode voltage drop; however, the horizontal current is reduced in the metal. The horizontal current magnitude for six different cathode materials in decreasing...
The Pidgeon process currently accounts for 85% of the world’s magnesium production. Although the Pidgeon process has been greatly improved over the past 10 years, such production still consumes much energy and material and creates much pollution. The present study investigates the process of producing magnesium by employing vacuum aluminothermic reduction and by using magnesite as material and obtaining...
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