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The direct photolyses of the γ-(3-methyl-1-phenyl-1,2-butadienyl)-substituted α,β-unsaturated esters and nitriles gave the bicyclo[2.1.0]pentanes, cross-conjugated trienes, and several intramolecular products, while the triplet-sensitization led to the former two compounds. It was found that the photochemoselectivity depended on the substituents on the vinyl group and would be controlled by the energy...
Pyrolysis and oxidation of ethylene were studied behind reflected shock waves in the temperature range 1100–2100 K at pressures of 1.5–4.5 atm. Ethylene decay in both the pyrolysis and oxidation reactions was measured by using both time-resolved IR-laser absorption at 3.39 μm and time-resolved IR-emission at 3.48 μm. CO 2 production in the oxidation was also measured by time-resolved IR-emission...
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