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A new Fe-based bulk metallic glass with superior glass-forming ability (GFA), Fe 46 Cr 15 Mo 14 C 15 B 6 Nb 4 , was developed based on the Fe–Cr–Mo–C–B alloy system by minor addition of Nb. The effects of Nb addition on glass formation of the Fe 50−x Cr 15 Mo 14 C 15 B 6 Nb x (x=0, 2, 4 and 6at...