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Eine neue Gold‐katalysierte Cycloisomerisierung von 1,6‐diinen wurde entwickelt, die einen atomökonomischen Zugang zu einem Satz verschiedenster Bicyclo[2.2.1]hept‐5‐en‐2‐onen in moderaten bis guten Ausbeuten darstellt. Für unsymmetrische Edukte mit zwei verschiedenen internen Alkinyl‐Substituenten konnte in einem gewissen Ausmaß die Regioselektivität sowohl durch elektronische als auch durch sterische...
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