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The effect of intramolecular crosslinking (IC) (cyclization) on gelation was studied using Monte Carlo simulations. The consumption of crosslinker in the IC process is proposed as one of the main reasons of significant overestimation of the gel point by Flory-Stockmayer theory. The system under study is atom transfer radical polymerization (ATRP) of a monomer and bifunctional (e.g. divinyl) crosslinker...
In this work we report a reproducible and efficient method of surface modification of titania nanoparticles (rutile) via reversible-deactivation radical polymerization. Herein, we graft poly(di(ethylene glycol) methyl ether methacrylate) from the surface of TiO2 in an amount of 21wt% within the reaction time of 3h 15min. The amount of grafted polymer was assessed by Thermogravimetric Analysis and...
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