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Inhibition of the mevalonate pathway by an HMG-CoA reductase inhibitor, mevalotin, in Streptomyces prunicolor possessing both mevalonate and MEP pathways resulted in the production of a new metabolite mevashuntin that consisted of conjugated thiazolone and pyranonaphthoquinone moieties.
Versipelostatin, a novel microbial metabolite consisting of a 17-membered macrocyclic aglycone with an α-acyltetronic acid functional group and sugar moieties was shown to be biosynthesized through a polyketide intermediate and the involvement of glyceric acid.
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