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The effects and feasibility of metal site doping of the tetragonal diamagnetic insulator FeGa3 by Fe/Co, Fe/Mn, and Co/Ni substitutions were investigated by the X-ray electron-probe microanalysis, electrical resistivity, specific heat, and magnetic susceptibility measurements. The substitution of Co for Fe in FeGa3 does not change its structural type and preserves the structure of the binary parent...
It is shown by x-ray diffraction, energy-dispersive x-ray spectrometry, and electron probe microanalysis that, at 800°C, the Ni–P system contains four phosphides in the composition range 25–33 at % P: Ni3P, Ni5P2 , Ni12P5 , and Ni2P. The structure of Ni5P2 is determined by single-crystal x-ray diffraction: sp. gr. P3¯c1, new structure type, a = 0.6613(3) nm, c = 1.2311(6) nm, 347 independent hklreflections...
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