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Fe–Si alloys are widely used for magnetic applications. However, it is very difficult to process Fe–Si with a silicon content exceeding 3.5wt.%Si (upper limit for products commercially available by the I/M route) due to the alloy's low ductility, which is attributed mainly to the formation of B2 and DO3 ordered phases that embrittle the material. To overcome this obstacle, the main focus of this work...