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p-Sexiphenyl(6P)/metal (Au, Mg) interfaces were studied by ultraviolet photoemission spectroscopy (UPS), X-ray photoemission spectroscopy (XPS), and metastable atom electron spectroscopy (MAES). The vacuum level shifts (Δ) at the interface were observed in both 6P/Au (Δ=−0.8±0.1 eV) and 6P/Mg (Δ=−0.4±0.1 eV) systems. The MAES spectra indicate that the 6P molecules are on the substrate with their mean...