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Graded (Ti1−xAlx)N coatings were prepared by reactive magnetron co-sputtering of Ti and Al on silicon and glass substrates in an Ar+N2 atmosphere. The N2 content was kept constant in the gas mixture and the composition of the (Ti1−xAlx)N film was controlled by the power applied to the targets. The composition of the graded films was determined by Auger electron spectroscopy (AES) depth profiling and...
High quality ZnGeP 2 (ZGP) crystals were grown by means of the horizontal gradient freezing technique and characterized by X-ray diffraction (XRD) and optical measurements. This compound solidifies congruently and on further cooling undergoes a β→α phase transition. At room temperature, the tetragonal α-ZGP crystals contained a small amount of coherently oriented cubic β-ZGP clusters, indicating...
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