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The effect of Na on highly dispersed FeOx impregnated onto CeO2 via the unique precursor Na/Fe-ethylenediaminetetraacetate (NaFeEDTA) was investigated by comparison to a series of well-defined catalysts synthesized by the traditional precursor Fe(NO3)3 both with and without Na addition. Catalysts were evaluated for steady-state NO reduction by CO and activities varied based on synthesis method and...
Silica-supported Pd and PdZn nanoparticles of a similar size were evaluated for neopentane hydrogenolysis/isomerization and propane hydrogenolysis/dehydrogenation. Monometallic Pd showed high neopentane hydrogenolysis selectivity. Addition of small amounts of Zn to Pd lead Pd–Zn scatters in the EXAFS spectrum and an increase in the linear bonded CO by IR. In addition, the neopentane turnover rate...
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