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A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H 2 PO 4− is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H 2 PO 4− in aqueous solution and at neutral pH. On the other hand, F − , Cl − ,...
As a versatile platform for phosphorescent chemosensors, bis(benzylic amine) derivative 6 was synthesized. Two urea groups could be readily introduced for phosphorescent chemosensor 1. A preorganized binding pocket could induce a selective phosphorescence enhancement with H2PO4−. A new iridium complex 2 bearing two thiourea groups as well as glucopyranosyl chiral barriers is reported as a first chiral...
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