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V-substituted LiMnPO 4 has been synthesized by the solid state reaction route. Combined Rietveld refinement of neutron and X-ray data revealed that all vanadium ions are located in the same positions as the phosphorus ions. The magnetic structure of LiMnP 0.85 V 0.15 O 4 was found to be the same as that described for undoped antiferromagnetic LiMnPO 4 (T ...