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The surface freezing (SF) of liquid 6-perfluorohexyl hexanol (F6H6OH)–1-dodecanol (C12OH) mixture was studied by surface tension, external reflection absorption FTIR (ERA-FTIR), and X-ray reflectivity (XR) measurements. The surface tension vs. temperature curve of pure C12OH liquid shows a sharp break point at the surface liquid (SL)–SF phase transition temperature Ts. The surface tension of pure...