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The thermal oxidation of 2-chlorophenol (2-CP) in air was investigated using a perfectly stirred reactor at 1atm over the temperature range 450–900°C. The relative concentration of 2-CP was 1000ppmV (equivalence ratio Φ=0.03). About fifty organic products were identified as trace species. The concentration profiles of 2-CP, carbon oxides as well as those of seventeen major organic intermediates and...