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The scope of metal loaded γ-Al2O3 materials as catalysts in the ozone initiated functionalisation of higher n-alkanes is investigated at moderate conditions (20 ± 1 °C and ∼1 atm). In the ozone initiated oxidation of the higher hydrocarbon, n-hexadecane with 0.5% Pd or Ni or V loaded γ-Al2O3 catalysts lead to the keto-isomers as main products, and organic acids as minor products. This paper emphasises...
Various nitroaromatics are successfully reduced to amines with 100% conversion and selectivity in methanol at low temperature (≈5 °C), by using versatile system of 5% Ni–SiO2 catalyst and NaBH4 and in situ generation of Ni boride. The catalytic efficiency of Ni loading (5%, 10% and 15%) with silica or titania as support materials is investigated for reduction of nitrobenzene. The Ni–titania/NaBH4...
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