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For the first time, a C60 derivative (1) and two different lanthanum metallofullerene derivatives, La@C82Py (2) and La2@C80Py (3), that feature a pyridyl group as a coordination site for transition‐metal ions have been synthesized and integrated as electron acceptors into coordinative electron‐donor/electron‐acceptor hybrids. Zinc tetraphenylporphyrin (ZnP) served as an excited‐state electron donor...
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