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Dimerization of a hydroxycarbazole produces an axially chiral biaryl, BICOL (2). One enantiomer (R)‐2, is capable of enantioselective binding to different polymorphs of DNA. The biaryl (R)‐2 was shown by fluorescence and circular dichroism to induce a shift of Z‐DNA to B‐DNA. The opposite enantiomer (S)‐2 shows no specific binding. The significant difference in behaviour between the two enantiomers...
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