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Hydrophilic polymer brushes grown via surface‐initiated ATRP from silicon oxide surfaces are susceptible to detachment via hydrolytic cleavage of the anchoring siloxane bond. This paper investigates the influence of the structure of the ATRP initiator on the stability of these brushes and seeks for strategies to further enhance their stability. It is found that increasing the hydrophobicity of the...
Nanoparticles working together. Thermoresponsive polymer‐coated nanoparticles are shown to display size dependent, cooperative, lower critical solution temperature behavior. This was exploited to direct the assembly of appropriate nanoparticles onto complementary polymer brush coated surfaces.
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