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A model polycyclic aromatic hydrocarbon (PAH) compound, anthracene, was incorporated into a thermosetting epoxy matrix as a reinforcing moiety via physical dispersion and/or chemical modification. In order to understand the “additive effect” of glass transition temperature (Tg) observed with the variation of free anthracene (AN) and bonded 2-aminoanthracene (2-AM) loading, the relaxation dynamics...
The use of vegetable oil macromonomers (VOMMs) as comonomers in emulsion polymerization enables good film coalescence without the use of solvents that constitute volatile organic compounds (VOCs). VOMMs are derived from renewable resources and offer the potential of post‐application crosslinking via auto‐oxidation. However, chain transfer reactions of VOMMs with initiator and/or polymer radicals during...
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