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We report significant improvements in the high-k/In0.53Ga0.47As interface quality by controlling atomic layer deposition (ALD) oxidizer chemistry. A step-by-step correlation between electrical data and chemical reactions at the high-k/InGaAs interface has been established using synchrotron photoemission. AsOx, GaOx, and In2O3 formed during unintentional ALD surface oxidation and the increase of As-As...
This paper details the use of vacuum ultraviolet (120 nm <; λ <; 800 nm) spectroscopic reflectivity to simultaneously measure AlOx and LaOx capping layers and the underlying high-k film stack system. It is demonstrated that the sensitivity of the method originates in the VuV portion of the spectra where absorption of these materials contributes significantly to the overall optical response....
The effect of flatband-voltage reduction [roll-off (R-O)], which limits fabrication options for obtaining the needed band-edge threshold voltage values in transistors with highly scaled metal/high- k dielectric gate stacks, is discussed. The proposed mechanism causing this R-O phenomenon is suggested to be associated with the generation of positively charged oxygen vacancies in the interfacial SiO...
This paper reports on a scalable and simple gate-first integration option for manufacturing the high-k/metal gate CMOS transistors targeting sub-32 nm LSTP applications: Vt < plusmn 0.45 V (at Lg = 60 nm) at EOT les 1.4 nm, with 105 times Jg reduction compared to SiO2. This scheme integrates several simplifications and improvements for the first time: single metal gate material, single channel...
Gate first 0.59 nm EOT HfOx/metal gate stacks for 16 nm node application are demonstrated for the first time. By controlling O during HfOx deposition, ldquozerordquo low-k SiOx interface (ZIL) forms despite a 1020degC activation anneal. This 0.59 nm EOT is a 30% improvement over a state of the art 32 nm HK/MG technology. We compare and demonstrate for the first time the improved scalability of ZIL...
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