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To probe the effect of valence electron concentration (vec or e–/atom) on γ‐Pd2+xZn11–x phases a series of compoundsPd2–xAuxZn11 (x = 0.3–0.8; e–/atom = 1.70–1.75) was synthesized and structurally characterized. The gold‐substituted γ‐brass type phase was observed for x ≤ 0.3, having a refined composition of Pd1.93Au0.27(1)Zn10.80(1) (space group I$\bar{4}$3m; a = 9.0953 (2) Å). Further addition of...