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Efficient nitric oxide (NO) removal without nitrogen dioxide (NO2) emission is desired for the control of air pollution. Herein, a series of (Zr/Ti)UiO‐66‐NH2 with congenetic shell–core structure, denoted as Ti‐UION, are rapidly synthesized by microwave‐assisted post‐synthetic modification for NO removal. The optimal Ti‐UION (i.e., 2.5Ti‐UION) exhibits the highest activity of 80.74% without NO2 emission...
Bimetallic MOF Photocatalysts
Ti atoms rapidly replace Zr atoms in UiO‐66‐NH2 crystal under microwave irradiation. The formed congenetic “shell‐core” structure and the introduced electron acceptor, Ti, enhance the photocatalytic nitric oxide (NO) removal. Furthermore, the synergy of NO photooxidation and subsequent NO2 adsorption not only removes NO efficiently in an environmentally friendly fashion,...
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