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Herein, lanthanum doping effects on the structural, dielectric, and electrical properties of Ba1−xLax(Zn1/3Nb2/3)O3 (BZN) solid solutions are focused upon. The La contents which are varied in the range of 0.02–0.20 exhibit a solubility limit of x = 0.02. Although minor phases of Ba5Nb4O15 and Ba3LaNb3O12 appear for samples doped with La contents of x = 0.05 and x = 0.10, they play no remarkable role...