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Formaldehyde is one of the most hazardous and typical indoor VOCs air pollutants. Asymmetric AgIO3 was respectively composited with 3D hierarchically structured BiOBr and 2D BiOBr nanosheets to photodegrade gas‐phase formaldehyde. Ag/AgIO3/BiOBr(CMC) demonstrated better photocatalytic performance than Ag/AgIO3/BiOBr owning to the role of biomass solvent sodium carboxymethyl cellulose in increasing...