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A novel biocompatible composite of poly(ε‐caprolactone) (PCL) was synthesized via in situ ring‐opening polymerization method of ε‐caprolactone in the presence of reduced graphene oxide (RGO). Fourier transform infrared (FTIR) and X‐ray photoelectron spectroscopy (XPS) studies support a strong interaction between PCL and RGO. The crystallization behavior and thermal stability of these composites were...