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Large surface area‐to‐volume ratios indoors cause heterogeneous interactions to be especially important. Semi‐volatile organic compounds can deposit on impermeable indoor surfaces forming thin organic films. We developed a new model to simulate the initial film formation by treating gas‐phase diffusion and turbulence through a surface boundary layer and multi‐layer reversible adsorption on rough surfaces,...
Emission, transport, and fate of semi‐volatile organic compounds (SVOCs), which include plasticizers, flame retardants, pesticides, biocides, and oxidation products of volatile organic compounds, are influenced in part by their tendency to sorb to indoor surfaces. A thin organic film enhances this effect, because it acts as both an SVOC sink and a source, thus potentially prolonging human exposure...
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