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Stabilized carbanions of malonates, 2‐phenylacetonitrile, or isopropyl 2‐phenylacetate add to m‐(trichloromethyl)nitrobenzene derivatives to form σH adducts that lose a chloride ion to give intermediate exo‐dichloromethylene nitrocyclohexadienes. These undergo re‐aromatization through 1,5‐hydrogen shift to yield tele substitution mono adducts. Depending on the stoichiometry of the nitroarene to the...