The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
A novel phosgene‐free route to different isocyanates starts from CO2 and aminosilanes (cf. silylamines) to form so‐called carbamoyloxysilanes (O‐silylcarbamates), i. e., compounds with the general motif R1R2N−CO−O−SiR3R4R5 as potential precursors. We focused on the insertion reaction of CO2 into Si−N bonds of substrates with cyclic (mostly aromatic) amine substituents, i. e., PhNHSiMe3, (PhNH)2SiMe...