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Metal‐organic frameworks are one of the most active research fields today. Despite the progress in recent years, synthesis of highly porous structures bearing functional groups for specific applications remains a challenge. Here, we describe synthesis of Zr(IV) and Hf(IV)‐based tetrazine containing metal‐organic frameworks, ZrTz‐68 and HfTz‐68 with pore size of 2.1 nm, specific surface area up to...