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For cobalt-catalyzed Fischer–Tropsch synthesis (FTS), a model was developed to analyze numerically the reaction–diffusion performance in catalyst particles. The model is based on a mesoporous particle and is valid for CO2-free and -rich syngas. The kinetic parameters of all three relevant reactions, CO hydrogenation to C2+ hydrocarbons as well as CH4 and CO2 hydrogenation (mainly) to CH4, were derived...
The production of liquid hydrocarbons based on CO2 and renewable H2 is a multi‐step process consisting of water electrolysis, reverse water‐gas shift, and Fischer‐Tropsch synthesis (FTS). The syngas will then also contain CO2 and probably sometimes H2O, too. Therefore, the kinetics of FTS on a commercial cobalt catalyst was studied with syngas containing CO, CO2, H2, and H2O. The intrinsic kinetic...
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