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In the crystal structure of 6‐methoxyquinoline N‐oxide dihydrate, C10H9NO2·2H2O, (I), the presence of two‐dimensional water networks is analysed. The water molecules form unusual water channels, as well as two intersecting mutually perpendicular columns. In one of these channels, the O atom of the N‐oxide group acts as a bridge between the water molecules. The other channel is formed exclusively by...