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The crystal structure of Blatter's radical (1,3‐diphenyl‐1,4‐dihydrobenzo[e][1,2,4]triazin‐4‐yl) has been investigated between ambient pressure and 6.07 GPa. The sample remains in a compressed form of the ambient‐pressure phase up to 5.34 GPa, the largest direction of strain being parallel to the direction of π‐stacking interactions. The bulk modulus is 7.4 (6) GPa, with a pressure derivative equal...