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The honeycomb porous films of tadpole‐shaped polyhedral oligomeric silsesquioxane fluorinated acrylates copolymers were fabricated through breath figure method. The static hydrophobic properties were studied through water contact angles (CAs) and the rim width/pore size (W/D) values. It was found that the low W/D value and high fluorine content generally indicated a high water CA. The properties such...