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The aim of this study was to design novel binary and ternary copolymers based on methacrylate and/or epoxy monomers reinforced with 10 wt % mono‐/octafunctional polyhedral oligomeric silsesquioxanes (POSS) compounds bearing one or eight epoxy or methacrylate moieties. The experimental parameters such as temperature and time of reaction, comonomer ratio and the incorporation of various types of POSS...