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Merging photoredox and catalysis by transition metals, coined as metallaphotoredox catalysis, proved to be an excellent new platform for the development of new synthetic strategies for the formation of carbon–carbon and carbon‐heteroatom bonds. Herein, we report a dual catalytic system that has been successfully developed for the azide‐alkyne ligation process to yield 1,4‐disubstituted‐1,2,3‐triazoles...